In Internet Explorer, browsing the following Federation Metadata endpoint fails:
https://{your_federation_service_name}/federationmetadata/2007-06/federationmetadata.xml
Internet Explorer displays the following error text:
Unable to download federationmetadata.xml from {your_federation_service_name}.
Unable to open this Internet site. The requested site is either unavailable or cannot be found. Please try again later.
Browsing to the other metadata endpoints is successful:
https://{your_federation_service_name}/adfs/fs/federationserverservice.asmx
https://{your_federation_service_name}/adfs/services/trust/mex
Disable IE ESC:
Windows Server 2003
Windows Server 2008 and later
If you discover that all metadata endpoints are unavailable, you need to troubleshoot:
1. Connectivity
2. SCHANNEL
3. Problems with the AD FS 2.0 service itself